Week 15
Endothermic
reaction:
- Put a small puddle of water on a block of wood.
- Place 20 g barium hydroxide and 10 g ammonium thiocyanate in a
50 ml beaker.
- Set the beaker in the water and stir the contents of the
beaker.
- The beaker will freeze to the board.
First-aid cold packs demonstrate spontaneous endothermic
reactions.
Break the water pouch and mix contents.
NH4NO3 (s) +
H2O (l)
NH4+(aq) +
NO3-(aq)
H = +26.2 kJ/mole = +326 J/g
Exothermic
reation:
- Before class, heat an amount of copper (II) sulfate
pentahydrate to drive off the water - it turns white.
- For the demonstration, add a small amount of water to the
white powder.
- Feel the beaker get hot.
First-aid hot packs demonstrate spontaneous exothermic
reactions.
Break the water pouch and mix contents.
CaCl2 (s) + H2O
(l)
Ca2+(aq) + 2Cl- (aq)
H = -82 kJ/mole = -747 J/g
Reaction Rate and Surface
Area:
- Place a small pile of flour on a metal tray and try to ignite
it with a bunsen burner.
- Fill a dropper pipet with the flour and shoot it across the
top of the burner flame.